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[Download] "Hydroboration and Organic Synthesis" by Ranjit S. Dhillon * eBook PDF Kindle ePub Free

Hydroboration and Organic Synthesis

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eBook details

  • Title: Hydroboration and Organic Synthesis
  • Author : Ranjit S. Dhillon
  • Release Date : January 01, 2007
  • Genre: Chemistry,Books,Science & Nature,Life Sciences,
  • Pages : * pages
  • Size : 12850 KB

Description

9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN’s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations.


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